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Beilstein J. Org. Chem. 2012, 8, 658–661, doi:10.3762/bjoc.8.73
Graphical Abstract
Scheme 1: Plausible mechanism for Tf2NH-catalyzed isomerization of silyl enol ethers.
Scheme 2: Regioselective formation of bicyclo[4.2.0]octanes from the same substrates by the isomerization–(2 ...
Scheme 3: Formation of bicyclo[5.2.0]octane from the regioisomeric mixture of silyl enol ethers.